ThuliumV1, Main, Exploration, bibRecord, 000831

Expanding the Series of [RE2Ca(OQ)8] Structures: New Heterobimetallic Rare Earth/Alkaline Earth 8‐Quinolinolate Complexes

Identifieur interne : 000831 ( Main/Exploration ); précédent : 000830; suivant : 000832

Expanding the Series of [RE2Ca(OQ)8] Structures: New Heterobimetallic Rare Earth/Alkaline Earth 8‐Quinolinolate Complexes

Auteurs : Glen B. Deacon [Australie] ; Peter C. Junk [Australie, États-Unis] ; Stuart G. Leary [Australie] ; Aron Urbatsch [Australie]

Source :

ZAAC ‐ Journal of Inorganic and General Chemistry [ 0044-2313 ] ; 2012-10.

RBID : ISTEX:DF3893F83254F7A1BE1297B82CB7B042F5E287B5

English descriptors

Abstract

Abstract. A series of heterobimetallic complexes [RE2Ca(OQ)8]·nHOQ(RE = Sm, Gd, Tb, Ho, Tm, Yb, Lu, Y, Sc) and the isostructural [Gd2Mg(OQ)8] were synthesised and structurally characterised. They were mainly obtained after direct reactions of the elemental rare earth metals with calcium metal in the presence of 8‐hydroxyquinoline (HOQ) and a 1, 3, 5‐tri‐tert‐butyl‐benzene (tBuB) flux, and some complexes were synthesised by pseudo solid‐state rearrangement reactions between powdered RE(OQ)3 and AE(OQ)2 (AE = Mg, Ca) in a 1, 2, 4, 5‐tetramethylbenzene (TMB) flux, at elevated temperatures. The linear trinuclear [RE2Ca(OQ)8] moieties show a six‐coordinate central calcium atom flanked by two eight‐coordinate rare earth atoms surrounded by six chelating‐bridging OQ and two terminal chelating OQ ligands. The structurally novel [Sc2Ca(OQ)8] has a bent Sc‐Ca‐Sc backbone and exhibits an eight‐coordinate central calcium and two seven‐coordinate scandium ions.

Url:

https://api.istex.fr/document/DF3893F83254F7A1BE1297B82CB7B042F5E287B5/fulltext/pdf

DOI: 10.1002/zaac.201200138

Affiliations:

Australie, États-Unis

Links toward previous steps (curation, corpus...)

to stream Istex, to step Corpus: 003134
to stream Istex, to step Curation: 003134
to stream Istex, to step Checkpoint: 000127
to stream Main, to step Merge: 000832
to stream Main, to step Curation: 000831

Le document en format XML

<record><TEI wicri:istexFullTextTei="biblStruct"><teiHeader><fileDesc><titleStmt><title xml:lang="en">Expanding the Series of [RE2Ca(OQ)8] Structures: New Heterobimetallic Rare Earth/Alkaline Earth 8‐Quinolinolate Complexes</title>
<author><name sortKey="Deacon, Glen B" sort="Deacon, Glen B" uniqKey="Deacon G" first="Glen B." last="Deacon">Glen B. Deacon</name>
</author>
<author><name sortKey="Junk, Peter C" sort="Junk, Peter C" uniqKey="Junk P" first="Peter C." last="Junk">Peter C. Junk</name>
</author>
<author><name sortKey="Leary, Stuart G" sort="Leary, Stuart G" uniqKey="Leary S" first="Stuart G." last="Leary">Stuart G. Leary</name>
</author>
<author><name sortKey="Urbatsch, Aron" sort="Urbatsch, Aron" uniqKey="Urbatsch A" first="Aron" last="Urbatsch">Aron Urbatsch</name>
</author>
</titleStmt>
<publicationStmt><idno type="wicri:source">ISTEX</idno>
<idno type="RBID">ISTEX:DF3893F83254F7A1BE1297B82CB7B042F5E287B5</idno>
<date when="2012" year="2012">2012</date>
<idno type="doi">10.1002/zaac.201200138</idno>
<idno type="url">https://api.istex.fr/document/DF3893F83254F7A1BE1297B82CB7B042F5E287B5/fulltext/pdf</idno>
<idno type="wicri:Area/Istex/Corpus">003134</idno>
<idno type="wicri:explorRef" wicri:stream="Istex" wicri:step="Corpus" wicri:corpus="ISTEX">003134</idno>
<idno type="wicri:Area/Istex/Curation">003134</idno>
<idno type="wicri:Area/Istex/Checkpoint">000127</idno>
<idno type="wicri:explorRef" wicri:stream="Istex" wicri:step="Checkpoint">000127</idno>
<idno type="wicri:doubleKey">0044-2313:2012:Deacon G:expanding:the:series</idno>
<idno type="wicri:Area/Main/Merge">000832</idno>
<idno type="wicri:Area/Main/Curation">000831</idno>
<idno type="wicri:Area/Main/Exploration">000831</idno>
</publicationStmt>
<sourceDesc><biblStruct><analytic><title level="a" type="main" xml:lang="en">Expanding the Series of [RE<hi rend="subscript">2</hi>
Ca(OQ)<hi rend="subscript">8</hi>] Structures: New Heterobimetallic Rare Earth/Alkaline Earth 8‐Quinolinolate Complexes
<ref type="figure" target="#f1"></ref>
</title>
<author><name sortKey="Deacon, Glen B" sort="Deacon, Glen B" uniqKey="Deacon G" first="Glen B." last="Deacon">Glen B. Deacon</name>
<affiliation wicri:level="1"><country xml:lang="fr">Australie</country>
<wicri:regionArea>School of Chemistry, Box 23, Monash University, Clayton, VIC 3800</wicri:regionArea>
<wicri:noRegion>VIC 3800</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Junk, Peter C" sort="Junk, Peter C" uniqKey="Junk P" first="Peter C." last="Junk">Peter C. Junk</name>
<affiliation wicri:level="1"><country xml:lang="fr">Australie</country>
<wicri:regionArea>School of Chemistry, Box 23, Monash University, Clayton, VIC 3800</wicri:regionArea>
<wicri:noRegion>VIC 3800</wicri:noRegion>
</affiliation>
<affiliation wicri:level="1"><country xml:lang="fr">Australie</country>
<wicri:regionArea>Present address: School of Pharmacy and, Molecular Sciences, James Cook University, Townsville, QLD 4811</wicri:regionArea>
<wicri:noRegion>QLD 4811</wicri:noRegion>
</affiliation>
<affiliation wicri:level="1"><country wicri:rule="url">États-Unis</country>
</affiliation>
<affiliation wicri:level="1"><country xml:lang="fr">Australie</country>
<wicri:regionArea>Correspondence address: School of Chemistry, Box 23, Monash University, Clayton, VIC 3800</wicri:regionArea>
<wicri:noRegion>VIC 3800</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Leary, Stuart G" sort="Leary, Stuart G" uniqKey="Leary S" first="Stuart G." last="Leary">Stuart G. Leary</name>
<affiliation wicri:level="1"><country xml:lang="fr">Australie</country>
<wicri:regionArea>School of Chemistry, Box 23, Monash University, Clayton, VIC 3800</wicri:regionArea>
<wicri:noRegion>VIC 3800</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Urbatsch, Aron" sort="Urbatsch, Aron" uniqKey="Urbatsch A" first="Aron" last="Urbatsch">Aron Urbatsch</name>
<affiliation wicri:level="1"><country xml:lang="fr">Australie</country>
<wicri:regionArea>School of Chemistry, Box 23, Monash University, Clayton, VIC 3800</wicri:regionArea>
<wicri:noRegion>VIC 3800</wicri:noRegion>
</affiliation>
</author>
</analytic>
<monogr></monogr>
<series><title level="j" type="main">ZAAC ‐ Journal of Inorganic and General Chemistry</title>
<title level="j" type="sub">Dedicated to Professor Rudolf Hoppe on the Occasion of His 90th Birthday</title>
<idno type="ISSN">0044-2313</idno>
<idno type="eISSN">1521-3749</idno>
<imprint><biblScope unit="vol">638</biblScope>
<biblScope unit="issue">12‐13</biblScope>
<biblScope unit="page" from="2001">2001</biblScope>
<biblScope unit="page" to="2007">2007</biblScope>
<biblScope unit="page-count">7</biblScope>
<publisher>WILEY‐VCH Verlag</publisher>
<pubPlace>Weinheim</pubPlace>
<date type="published" when="2012-10">2012-10</date>
</imprint>
<idno type="ISSN">0044-2313</idno>
</series>
</biblStruct>
</sourceDesc>
<seriesStmt><idno type="ISSN">0044-2313</idno>
</seriesStmt>
</fileDesc>
<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Acta crystallogr</term>
<term>Allg</term>
<term>Anorg</term>
<term>Bond lengths</term>
<term>Bruker apex</term>
<term>Calcium metal</term>
<term>Central calcium atom</term>
<term>Chem</term>
<term>Chemical formula formula mass crystal system space group</term>
<term>Complexes compound reference</term>
<term>Coordination number</term>
<term>Crystal structure</term>
<term>Crystallographic data</term>
<term>Dalton trans</term>
<term>Diffraction data</term>
<term>Direct metal reactions</term>
<term>Earth atoms</term>
<term>Enraf nonius kappa</term>
<term>Final values</term>
<term>Formula units</term>
<term>Glass tube</term>
<term>Gmbh</term>
<term>Heterobimetallic</term>
<term>Heterobimetallic complexes</term>
<term>Hydrogen atoms</term>
<term>Independent reflections rint</term>
<term>Inert flux tbub</term>
<term>Inorg</term>
<term>Kgaa</term>
<term>Lanthanoid</term>
<term>Lanthanoid contraction</term>
<term>Lanthanoid series</term>
<term>Ligand</term>
<term>Metal ions</term>
<term>Mmol</term>
<term>Nitrogen atoms</term>
<term>Nujol</term>
<term>Other complexes</term>
<term>Oxygen atoms</term>
<term>Rare earths</term>
<term>Rearrangement reactions</term>
<term>Same stoichiometry</term>
<term>Scandium</term>
<term>Scandium ions</term>
<term>Several days</term>
<term>Single crystals</term>
<term>Tbub</term>
<term>Terminal chelating</term>
<term>Thermal ellipsoids</term>
<term>Triclinic</term>
<term>Trigonal geometry</term>
<term>Unit cell</term>
<term>Verlag</term>
<term>Verlag gmbh</term>
<term>Weinheim</term>
</keywords>
<keywords scheme="Teeft" xml:lang="en"><term>Acta crystallogr</term>
<term>Allg</term>
<term>Anorg</term>
<term>Bond lengths</term>
<term>Bruker apex</term>
<term>Calcium metal</term>
<term>Central calcium atom</term>
<term>Chem</term>
<term>Chemical formula formula mass crystal system space group</term>
<term>Complexes compound reference</term>
<term>Coordination number</term>
<term>Crystal structure</term>
<term>Crystallographic data</term>
<term>Dalton trans</term>
<term>Diffraction data</term>
<term>Direct metal reactions</term>
<term>Earth atoms</term>
<term>Enraf nonius kappa</term>
<term>Final values</term>
<term>Formula units</term>
<term>Glass tube</term>
<term>Gmbh</term>
<term>Heterobimetallic</term>
<term>Heterobimetallic complexes</term>
<term>Hydrogen atoms</term>
<term>Independent reflections rint</term>
<term>Inert flux tbub</term>
<term>Inorg</term>
<term>Kgaa</term>
<term>Lanthanoid</term>
<term>Lanthanoid contraction</term>
<term>Lanthanoid series</term>
<term>Ligand</term>
<term>Metal ions</term>
<term>Mmol</term>
<term>Nitrogen atoms</term>
<term>Nujol</term>
<term>Other complexes</term>
<term>Oxygen atoms</term>
<term>Rare earths</term>
<term>Rearrangement reactions</term>
<term>Same stoichiometry</term>
<term>Scandium</term>
<term>Scandium ions</term>
<term>Several days</term>
<term>Single crystals</term>
<term>Tbub</term>
<term>Terminal chelating</term>
<term>Thermal ellipsoids</term>
<term>Triclinic</term>
<term>Trigonal geometry</term>
<term>Unit cell</term>
<term>Verlag</term>
<term>Verlag gmbh</term>
<term>Weinheim</term>
</keywords>
</textClass>
</profileDesc>
</teiHeader>
<front><div type="abstract">Abstract. A series of heterobimetallic complexes [RE2Ca(OQ)8]·nHOQ(RE = Sm, Gd, Tb, Ho, Tm, Yb, Lu, Y, Sc) and the isostructural [Gd2Mg(OQ)8] were synthesised and structurally characterised. They were mainly obtained after direct reactions of the elemental rare earth metals with calcium metal in the presence of 8‐hydroxyquinoline (HOQ) and a 1, 3, 5‐tri‐tert‐butyl‐benzene (tBuB) flux, and some complexes were synthesised by pseudo solid‐state rearrangement reactions between powdered RE(OQ)3 and AE(OQ)2 (AE = Mg, Ca) in a 1, 2, 4, 5‐tetramethylbenzene (TMB) flux, at elevated temperatures. The linear trinuclear [RE2Ca(OQ)8] moieties show a six‐coordinate central calcium atom flanked by two eight‐coordinate rare earth atoms surrounded by six chelating‐bridging OQ and two terminal chelating OQ ligands. The structurally novel [Sc2Ca(OQ)8] has a bent Sc‐Ca‐Sc backbone and exhibits an eight‐coordinate central calcium and two seven‐coordinate scandium ions.</div>
</front>
</TEI>
<affiliations><list><country><li>Australie</li>
<li>États-Unis</li>
</country>
</list>
<tree><country name="Australie"><noRegion><name sortKey="Deacon, Glen B" sort="Deacon, Glen B" uniqKey="Deacon G" first="Glen B." last="Deacon">Glen B. Deacon</name>
</noRegion>
<name sortKey="Junk, Peter C" sort="Junk, Peter C" uniqKey="Junk P" first="Peter C." last="Junk">Peter C. Junk</name>
<name sortKey="Junk, Peter C" sort="Junk, Peter C" uniqKey="Junk P" first="Peter C." last="Junk">Peter C. Junk</name>
<name sortKey="Junk, Peter C" sort="Junk, Peter C" uniqKey="Junk P" first="Peter C." last="Junk">Peter C. Junk</name>
<name sortKey="Leary, Stuart G" sort="Leary, Stuart G" uniqKey="Leary S" first="Stuart G." last="Leary">Stuart G. Leary</name>
<name sortKey="Urbatsch, Aron" sort="Urbatsch, Aron" uniqKey="Urbatsch A" first="Aron" last="Urbatsch">Aron Urbatsch</name>
</country>
<country name="États-Unis"><noRegion><name sortKey="Junk, Peter C" sort="Junk, Peter C" uniqKey="Junk P" first="Peter C." last="Junk">Peter C. Junk</name>
</noRegion>
</country>
</tree>
</affiliations>
</record>

Pour manipuler ce document sous Unix (Dilib)

EXPLOR_STEP=$WICRI_ROOT/Wicri/Terre/explor/ThuliumV1/Data/Main/Exploration

HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 000831 | SxmlIndent | more

HfdSelect -h $EXPLOR_AREA/Data/Main/Exploration/biblio.hfd -nk 000831 | SxmlIndent | more

Pour mettre un lien sur cette page dans le réseau Wicri

{{Explor lien
   |wiki=    Wicri/Terre
   |area=    ThuliumV1
   |flux=    Main
   |étape=   Exploration
   |type=    RBID
   |clé=     ISTEX:DF3893F83254F7A1BE1297B82CB7B042F5E287B5
   |texte=   Expanding the Series of [RE2Ca(OQ)8] Structures: New Heterobimetallic Rare Earth/Alkaline Earth 8‐Quinolinolate Complexes
}}

This area was generated with Dilib version V0.6.21.
Data generation: Thu May 12 08:27:09 2016. Site generation: Thu Mar 7 22:33:44 2024

	Serveur d'exploration sur le thulium
	Attention, ce site est en cours de développement ! Attention, site généré par des moyens informatiques à partir de corpus bruts. Les informations ne sont donc pas validées.

Serveur d'exploration sur le thulium

Expanding the Series of [RE2Ca(OQ)8] Structures: New Heterobimetallic Rare Earth/Alkaline Earth 8‐Quinolinolate Complexes

Expanding the Series of [RE2Ca(OQ)8] Structures: New Heterobimetallic Rare Earth/Alkaline Earth 8‐Quinolinolate Complexes

Source :

English descriptors

Abstract

Links toward previous steps (curation, corpus...)

Le document en format XML

Pour manipuler ce document sous Unix (Dilib)

Pour mettre un lien sur cette page dans le réseau Wicri